Asymmetric Reductions

  • Asymmetric Hydrogenation: Overview chiral rhodium or ruthenium complexes and their use in enantioselective hydrogenation.
  • Asymmetric Transfer Hydrogenation: Overview of organocatalysts and mechanisms for inducing chirality.
  • Asymmetric Hydride Reductions: Chiral borohydrides and CBS catalysts for selective reduction of ketones and imines.

Asymmetric Hydroboration

  • Hydroboration-Oxidation Reactions: Explore chiral borane reagents and their use in enantioselective hydroboration.
  • Mechanistic Aspects: Discuss how chiral induction is achieved and how it affects the outcome of hydroboration reactions.