This spreadsheet below shows two methods to determine the population standard deviation for a set of measurements.
Suppose you have 5 mass measurements for 10 mL samples of water. The mass measurements are 9.97 g, 9.99 g, 10.01 g, 10.02 g and 9.98 g.
There is a built-in function in Google sheets (also in Excel - STDEV.P) to determine the standard deviation. This function was used in cell D18 below.