NAS - Elimination/Addition - Benzyne

Introduction to NAS

In the presence of a more powerful base/nucleophile or at higher temperatures a different mechanism for NAS can occur.  While studying NAS reactions, researcher encountered some unexpected regichemistry.

When they labeled the carbon attached to the Cl atom with a ¹³C they observed the following two products in equal amounts.

They proposed the following elimiation/addition sequence and proved it by traping the benzyne intermediate.

The benzyne intermediate was trapped with 1,3-butadiene via a Diels-Alder reaction.  See if you can predict the Diels Alder product.