Calculating Reaction Yields


Background: Theory vs. Reality

Theoretical Yield: The maximum amount of product that can be produced based on stoichiometry.

Actual Yield: The amount of product physically obtained in the lab.

Percent Yield:

Percent Yield = Actual Yield Theoretical Yield × 100%


Problem 1

Ca + Cl2 → CaCl2
A chemist wants to produce exactly 45.0 g of CaCl2. Determine the required moles and grams of Ca and Cl2.

Step 1 (Part A): Determining Required Reactants

Step 1: Convert 45.0 g CaCl₂ to moles

45.0 g CaCl2 × 1 mol CaCl2 110.98 g CaCl2 = 0.405 mol CaCl2


Step 2: Determine moles of Ca required

0.405 mol CaCl2 × 1 mol Ca 1 mol CaCl2 = 0.405 mol Ca

Convert moles Ca to grams

0.405 mol Ca × 40.08 g Ca 1 mol Ca = 16.2 g Ca


Step 3: Determine moles of Cl₂ required

0.405 mol CaCl2 × 1 mol Cl2 1 mol CaCl2 = 0.405 mol Cl2

Convert moles Cl₂ to grams

0.405 mol Cl2 × 70.90 g Cl2 1 mol Cl2 = 28.7 g Cl2

To produce 45.0 g CaCl2 (Theoretical Yield):

Required Ca: 0.405 mol = 16.2 g
Required Cl2: 0.405 mol = 28.7 g

Step 2 (Part B): Calculating Actual Yield

After performing the reaction, the chemist collects only 39.6 g of CaCl2.

Percent Yield = 39.6 g 45.0 g × 100 = 88.0%

Percent Yield = 88.0%

Problem 2

Balanced Chemical Equation

4Al + 3O2 → 2Al2O3

The chemist wants to produce 100.0 g of Al2O3. Determine the moles and grams of Al and O2 needed.

Step 1 (Part A): Determining Required Reactants

Step 1: Convert grams Al₂O₃ to moles

100.0 g Al2O3 × 1 mol Al2O3101.96 g Al2O3 ≈ 0.980 mol Al2O3

Step 2: Determine moles of Al required

0.980 mol Al2O3 × 4 mol Al2 mol Al2O3 = 1.960 mol Al

Convert moles Al to grams

1.960 mol Al × 26.98 g Al1 mol Al ≈ 52.9 g Al

Step 3: Determine moles of O₂ required

0.980 mol Al2O3 × 3 mol O22 mol Al2O3 = 1.470 mol O2

Convert moles O₂ to grams

1.470 mol O2 × 32.00 g O21 mol O2 ≈ 47.0 g O2

To produce 100.0 g Al2O3 (Theoretical Yield):
Required Al: 1.960 mol ≈ 52.9 g
Required O2: 1.470 mol ≈ 47.0 g

Step 2 (Part B): Calculating Percent Yield

After performing the reaction, only 92.0 g of Al2O3 is collected.

Percent Yield = 92.0 g100.0 g × 100 ≈ 92.0%

Percent Yield = 92.0%